Settings seem ok, other than temp may be a touch high (esp for the wide-bore nozzle)? I get away with about 230C most of the time with an 0.4mm nozzle (albeit only running at c. 60 mm/s), this varies between people (and preference) and your numbers aren't silly.
That said, definitely shouldn't be any burning like that. Have you updated the firmware to reflect the new sensor for the E3D, or did you reuse the old sensor? Is the sensor installed securely?
The free extrusion swelling, and that being different depending on speed is pretty normal: it's called "die swell" - the filastruder peeps on this forum discuss it in great detail. The volume coming out is dependent on the volume going in, so this is probably not a problem for you.
Have you calibrated the steps-per-mm again for the new setup (didn't change much when I put my E3D on), and done a wall-thickness calibration again? Could be a wee bit of overextrusion.
Apologies, lots of questions, but lots of possible causes! 
SD3. Mk2b + glass, heated enclosure, GT2 belts, direct drive y shaft, linear bearings, bowden-feed E3D v5 w/ 0.9° stepper
Smoothieboard via Octoprint on RPi