Hey goik, have you actually seen a 3d printed model with an fdm/fff printer?
Even at 100 microns, I don't think they are that great for stuff like iphone cases and not something that can be finished properly with sandpaper, acetone, etc. because its hard to do that on a symmetric model.
For stuff like small statues, vases, other decorative objects I guess after finishing it will look good enough for people to buy. But make sure for vases that its water-tight.
phone car/bycicle mounts, other accessories for phones, GoPro etc I guess the unfinished look won't matter for the customer.
Printing things for hobbyists and thinkerers (like quadcopter parts, GoPro accessories, Arduino cases, etc.) and replacement parts for old things you can't find replacement parts for anymore is I think the best way to earn some money from FFF 3d printers.
Maybe you should also learn how to make sand or silicone molds if you're planning to sell more than one of the same item.
For all the above you'll need to know 3d modelling, or get a 3d modeller to work with you.
With SLA printers I think the quality is not an issue as some of those can print at 25 microns, but those have limitations too. Don't remember what though except limited materials you can print with and higher prices.
This is just from my experience. Someone correct me if I'm wrong on something here.
Also you might wanna get a extruder/winder to make your own filament. If you're planning to use a printer for business, you'll spend about $300-500 once and then something like $7 for 1 kg of the plastic pellets for making your own filament instead of $30 for buying the same 1 kg of filament from others.
Good luck.