Downloading the new Blender to tinker with now!
Another nice feature of Blender is the 'beautify fill' option. If you have a set of vertices in one plane and you want to create a face, Alt+F fills it with triangles, but arranges them so as to minimise the longer thin triangles, making a better shape for printing. Blender has loads of these little things that work really well, but you may never know they're there.
Also, something that caught me out at first... the export STL option does not assume you want to export everything if nothing is selected. It assumes you want to export nothing, and generates a blank stl file.
*edit
Tried the new Blender now. Some very nice features. For example, it can turn your model into a live heat map with the new mesh analysis tool. Worse overhangs will be highlighted more intensely. You can also set it to highlight thin edges, or sharp edges, or more. The new tools are just present without changing the normal use of Blender if you have them switched off.